Stepwise alkyne insertion in Au(I) acetylides: influence of the nuclearity


Chem. Sci., 2025, 16,4684-4694
DOI: 10.1039/D4SC08227C, Edge Article
Open Access Open Access
Juan Cayuela-Castillo, Francisco J. Fernández-de-Córdova, Matthew S. See, Israel Fernández, Pablo Ríos
The influence of the second metal atom in neutral σ,σ bimetallic gold(I) acetylides is studied in detail in the context of the migratory insertion of a number of substrates, where the reaction conditions depend dramatically on the nuclearity.
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