The study of the interaction between polymers and light has significantly bloomed over the past few years in various fundamental research and applications. The relationship between polymers and light can be beneficial (we refer to this as “love”) or be destructive (we refer to this as “hate”). It is important to understand the nature of both these love and hate relationships between polymers and light to apply these concepts in various future systems, to surpass performance of existing materials, or to mitigate some problems associated with polymers. Therefore, this perspective highlights both the photophilic (e.g., photopolymerization, rate modulation, temporal/spatial control, drug delivery, waste management, photo functionalization, and photo-enhanced depolymerization) and photophobic (e.g., photodegradation, discoloration, optical density, and loss of functionality) nature of polymers.