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Energy and Environment

Photocatalytic 1,3-difluoroalkylcarboxylation of alkenes by triple kinetic-controlled radical self-ordering

admin March 8, 2025 No Comments

A transition-metal-free protocol for the unsymmetrical radical 1,3-difunctionalization of alkenes has been established for the first time in the form of 1,3-difluoroalkylcarboxylation by a photocatalytic radical three-component reaction of allyl…

Energy and Environment

An argument for abandoning the “allowed” and “forbidden” classification of electrocyclic reactions

admin March 8, 2025 No Comments

The division of electrocyclic reactions into “allowed” and “forbidden” classes carries the implication that reactions of the latter class are so energetically penalised that they will occur only if their…

Energy and Environment

Correction: Construction of an autocatalytic reaction cycle in neutral medium for synthesis of life-sustaining sugars

admin March 8, 2025 No Comments

Chem. Sci., 2025, 16,4549-4549DOI: 10.1039/D5SC90052B, Correction Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Hiro Tabata, Genta Chikatani, Hiroaki Nishijima, Takashi Harada, Rika…

Energy and Environment

Unraveling the Effect of Alkali Cation on Fe Single Atom Catalysts with High Coordination Number

admin March 8, 2025 No Comments

Fe single atom catalysts (SACs) with high coordination number have emerged as high-performance catalysts for the conversion of CO2 to CO. However, the influence of alkali cation at the catalyst-electrolyte…

Fitness

C.D.C. Will Investigate Debunked Link Between Vaccines and Autism

admin March 8, 2025 No Comments

The Centers for Disease Control and Prevention is planning to conduct a large-scale study to re-examine whether there is a connection between vaccines and autism, federal officials said Friday. Dozens…

Energy and Environment

Bifunctional Additive-Driven Shape Transitions of Block Copolymer Particles through Synergistic Quaternization and Protonation

admin March 8, 2025 No Comments

Block copolymer (BCP) particles with tailored shapes and nanostructures hold promise for applications in cell adhesion, photonic system, and energy storage due to their unique optical and rheological properties. Conventional…

Fitness

Trump Administration Sends Politically Charged Survey to Researchers

admin March 8, 2025 No Comments

The Trump administration has asked researchers and organizations whose work is conducted overseas to disclose ties to those regarded as hostile, including “entities associated with communist, socialist or totalitarian parties,”…

Energy and Environment

Tuning biological processes via co-solutes: from single proteins to protein condensates – the case of α-elastin condensation

admin March 8, 2025 No Comments

Protein condensates as membrane-less compartments play a pivotal role in cellular processes. The stabilization of protein condensation can be tuned using cosolutes which directly impact biological function. In this study,…

Fitness

What Is Hantavirus, the Rare Disease That Killed Betsy Arakawa?

admin March 8, 2025 No Comments

Betsy Arakawa, the wife of Gene Hackman, died from the effects of hantavirus, a rare disease often caused by contact with droppings from infected rodents. Hantavirus does not spread among…

Energy and Environment

Thermal- and light-induced valence tautomerism with a concerted spin transition in an iron tris(diimine) complex

admin March 7, 2025 No Comments

The switching phenomena of spin crossover (SCO) and valence tautomerism (VT) are respectively dominated by iron(II) and cobalt-dioxolene systems. To explore new possibilities for SCO or VT, the redox-active α-diimine…

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Fitness

For Some, Return of Presidential Fitness Test Revives Painful Memories

technology

Met Police to double facial recognition use amid budget cuts

Fitness

Radioactive Wasps Found at Nuclear Site in South Carolina Could Be a ‘Red Flag,’ Expert Says

technology

Securing agentic identities focus of Palo Alto’s CyberArk buy

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