Electrically conductive charge-segregated pseudo-polymorphs comprising highly planar expanded π-electronic cations

Chem. Sci., 2025, 16,4998-5006
DOI: 10.1039/D4SC07576E, Edge Article

Open Access

&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Yohei Haketa, Ryoya Nakajima, Yuto Maruyama, Hiroki Tanaka, Wookjin Choi, Shu Seki, Shunsuke Sato, Hitomi Baba, Yoshiki Ishii, Go Watanabe, Kirill Bulgarevich, Kazuo Takimiya, Kenzo Deguchi, Shinobu Ohki, Kenjiro Hashi, Takashi Nakanishi, Yukihide Ishibashi, Tsuyoshi Asahi, Kazuchika Ohta, Hiromitsu Maeda
Ion pairs of a benzoporphyrin Au^III complex as a planar expanded π-electronic cation exhibited anion-dependent charge-segregated assemblies in pseudo-polymorphs of single-crystal and less-crystalline states, exhibiting electric conductivity properties.
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