Broderick and Herbert’s article (D. R. Broderick and J. M. Herbert, Chem. Sci., 2024, 15, 19893–19906, https://doi.org/10.1039/D4SC05955G) explores an open concern about using energies from density-functional approximations when developing force…
Azidoalkyation is an efficient strategy for the conversion of unsaturated precursors into nitrogen-containing structural motifs. Herein, we describe a convenient and highly regioselective iron-catalyzed 1,2-azidoalkylation of 1,3-dienes that employs TMSN3…
Photocages are protecting groups that can be unmasked with light irradiation and provide spatiotemporal control over the activity of a biomolecule. Ideally, photocages have high quantum yields for deprotection and…
Chem. Sci., 2025, Accepted ManuscriptDOI: 10.1039/D4SC07570F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Hariom Birla, Showkat Mir, Khushboo Yadav, Thomas…
Bimetallic heterogeneous catalysts combining group 9 metals (Rh, Ir) or group 10 metals (Ni, Pd, Pt) with Mo on a silica-based support have been synthesized via surface organometallic chemistry and…
Near-infrared (NIR) light activatable photosensitizers (PSs) garnered tremendous interest as PSs for photodynamic therapy (PDT) due to the deeper tissue penetration ability and least toxicity of NIR radiation. However, low…
Water-air nanointerfaces are essential components of multiphase electrochemical processes in various energy-related applications, including water electrolysis, hydrogen fuel cells, and CO2 electrochemical reduction. Deep insights into the critical properties of…
Heterometal doping in polyoxometalates (POMs) is a useful strategy to impart modular reactivity by leveraging control over the physicochemical properties of the resulting materials. The dopant can occupy different position(s)…
Alkene hydroboration provides a convenient route to generate organoborane synthons and recent efforts to develop catalysts for this and many other organic transformations have involved a shift to Earth-abundant first…
The electrochemical CO2 reduction reaction (CO2RR), as a novel technology, holds great promise for carbon neutrality. Immobilized molecular catalysts are considered efficient CO2RR catalysts due to their high selectivity and…
admin