Herein, we report a metal-free divergent visible-light driven method for the synthesis of fluorinated sulfoximines. Both olefins and propellanes efficiently undergo difluorosulfoximination with yields up to 77% (65 examples). The…
Chem. Sci., 2025, 16,4684-4694DOI: 10.1039/D4SC08227C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Juan Cayuela-Castillo, Francisco J. Fernández-de-Córdova, Matthew S. See,…
Machine learning (ML) has emerged as a powerful tool to navigate polymer structure–property relationships. Despite recent progress, data sparsity is a major obstacle hindering the practical application of ML in…
Solar-driven catalytic conversion of carbon dioxide (CO2) into value-added C2+ chemicals and fuels has attracted significant attention over the past decades, propelled by urgent environmental and energy demands. However, the…
Epidermal growth factor receptor (EGFR) homodimers and heterodimers play significant roles in a variety of tumors, but current imaging probes remain problematic due to restricted contrast and sensitivity. Thus, we…
The favorable excited-state dynamics, nonlinear optics, and extraordinary phototheranostic capabilities of conjugated metallaaromatics are attractive topics of research. A promising and multifunctional photosensitizer, double-phenanthroline-carbolong DPC, was investigated comparatively. It featured…
Despite recent advances in the synthesis of aza-bicycloheptanes (aza-BCHeps, which have an sp3-hybridized nitrogen atom) and azabicycloheptenes (aza-BCHepes, which have an sp2-hybridized nitrogen atom), which are bioisosteres of pyridine, construction…
Electrolytic hydrogen is identified as a crucial component in the desired decarbonisation of the chemical industry, utilizing renewable energy to split water into hydrogen and oxygen. Water electrolysis still requires…
Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC90062J, Editorial Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wei-Xiong Zhang, Cheng-Yong Su, Xiao-Ming Chen, Song GaoCelebrating…
We have utilized a modular on-strand Aldol approach to synthesize chalcone-based fluorescent molecular rotors (FMRs) bearing phenolic oxygen donors that mimic the natural tyrosine (Tyr66) chromophore 4-hydroxybenzylidene-imidazolinone (HBI) within green…
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