Coordination of Cm(III) with a chiral decadentate ligand N,N,N′,N′-tetrakis-1,2-diaminocyclohexane (tpadac) generated complexes with strong luminescence allowing for the unprecedented measurement of well-resolved Cm(III) circularly polarized luminescence spectra. Quantitative resolution of…
TiO2 has garnered significant attention in the field of photoelectrochemical (PEC) water splitting due to its non-toxicity, cost-effectiveness, and exceptional photochemical stability. However, its practical efficiency in H2 production is…
We report a method for the site- and stereoselective intramolecular amination of electron-deficient heterobenzylic C–H bonds via silver-catalyzed nitrene transfer (NT). A silver complex supported by a tripodal piperidine-based ligand…
Designing sorbents for the separation of molecules with sub-angstrom differences in size requires precise control over pore size and environment, which can be challenging to establish in the presence of…
The investigation of material properties based on atomic structure is a commonly used approach. However, in the study of complex systems such as high-entropy alloys, atomic structure not only covers…
Protein lipoylation is a post-translational modification (PTM) of great significance as the lipoylation sites have essential effects on the enzymatic activities of several protein complexes, which affect the biological metabolic…
Organic luminescent radicals, with their open-shell electronic structure, exhibit appealing optoelectronic properties and hold promise for a wide range of potential applications. Although a few series of luminescent radicals have…
Chem. Sci., 2025, 16,4614-4624DOI: 10.1039/D5SC00524H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Simone Scintilla, Daniele Rossetto, Martin Clémancey, Julia Rendon,…
RNA is a multifaceted biomolecule with numerous biological functions and can interact with small molecule metabolites as exemplified by riboswitches. Here, we profile the Escherichia coli transcriptome on interactions with…
Interfacial whole-cell biocatalysis has great potential for advanced chemical synthesis due to its ability to efficiently mediate complex reactions. However, the practical use of this approach is often limited by…
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