Guided by principles of reticular chemistry, we have successfully presented the “bending-bridge” strategy, achieving an extraordinary function-targeted assembly by ingeniously redirecting the coordination direction of traditional SBUs. This led to…
The electrochemical nitrate reduction reaction (NO3RR) offers a “two-birds-one-stone” solution by simultaneously addressing water pollution and enabling green ammonia production. However, its multiple reaction pathways and complex intermediates pose a…
Due to its electron deficiency, boron triple bonds are relatively scarce. We use high-resolution photoelectron imaging to investigate the structures and bonding of EB2O− (E = P, As) type of…
Predicting reaction kinetics in aqueous microdroplets, including aerosols and cloud droplets, is challenging due to the probability that the underlying reaction mechanism can occur both at the surface and in…
Pathogenic Staphylococcus aureus causes most infectious disease related deaths in the developed world. Continuously evolving resistance to clinically approved antibiotics and combination therapies limits tratment efficacy; new strategies that evade…
Here, we show mechanistic analyses of solid-state temperature-dependent luminescence of C,C′-diaryl-o-carborane derivatives. Solid-state stimuli-responsiveness is a promising property to visualize environmental changes on the molecular scale. Thus, mechanistic study of…
The synthesis of an arsanyl-phosphagallene 2AsP=Ga(NacNac) (NacNac = HC2; Dipp = diisopropylphenyl) and its reactivity towards heterocumulenes and ketones is described. Reactions with azides, carbodiimides, isocyanates and ketones give rise…
Iterative catalysis is a unique characteristic of the biosynthesis of ribosomally synthesized and post-translationally modified peptides (RiPPs) to boost structural and biological diversity. Lasso peptides are an abundant class of…
Reaching out to the distal sp3 C‒H bonds remain a daunting challenge to synthetic organic chemists primarily due to the relative inertness of C‒H bond in alkanes. As such, most…
In-brief analysis March 17, 2025 Data source: U.S. Energy Information Administration, U.S. Natural Gas Pipeline Projects trackerNote: Map includes pipeline projects of more than…
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