Single-atom catalysts (SACs) with M-N4 active sites show great potential to catalyze the electrochemical CO2 reduction reaction (eCO2RR) toward CO. The activity and selectivity of SACs are determined by the…
Abnormal cancer metabolism causes hypoxia and immunosuppression, limiting the anti-tumor efficacy of radiotherapy. Herein, we report a positively charged, mitochondria-targeted nanoscale metal–organic layer conjugated with 3-bromopyruvate (BP), BP/Hf12-Ir, for metabolic…
Accurate estimation of protein–ligand (PL) binding free energies is a crucial task in medicinal chemistry and a critical measure of PL interaction modeling effectiveness. However, traditional computational methods are often…
Elucidating the ultrafast dynamics of interfacial molecules at the single-molecule level is pivotal for advancing our understanding of fundamental chemical and biological processes. Here, for the first time, we realized…
Room-temperature phosphorescent (RTP) single crystals of covalent organic polymers (COPs) are rarely reported due to the huge challenge in preparing single crystals from solutions as well as the difficulty in…
Biological membranes play a major role in diffusing protons on their surfaces between transmembrane protein complexes. The retention of protons on the membrane’s surface is commonly described by a membrane-associated…
Herein, we report the preparation of a series of metallacycle-cored liquid crystals with hexagonal and trigonal symmetries based on the self-assembly of tri(ethyl glycol) (TEG)-functionalized diplatinum(II) ligands and alkyl chain-appendant…
The electrochemical CO2 reduction reaction (eCO2RR) has gained widespread attention as an important technology for carbon cycling and sustainable chemistry. In situ Raman spectroscopy, due to its molecular structure, sensitive…
The presence of water in organic solvents is a ubiquitous fact and can affect the reactivity and selectivity of chemical reactions. Traditional physical and chemical methods (IR, NMR, Karl Fischer…
Fluoride-ion batteries are a promising alternative to lithium-ion batteries by dint of the greater crustal abundance of fluorine and the potential to alleviate the need for metal electrodeposition. However, conventional…
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