The switching phenomena of spin crossover (SCO) and valence tautomerism (VT) are respectively dominated by iron(II) and cobalt-dioxolene systems. To explore new possibilities for SCO or VT, the redox-active α-diimine…
Biomass-derived carbon dots (BCDs) have attracted considerable attention for their promising attributes, including low toxicity, excellent solubility, biocompatibility, and eco-friendliness. Their rich surface chemistry and impressive photoluminescent properties have sparked…
Transitioning the chemical industry away from fossil fuels is a critical goal that requires the adoption of alternative, non-fossil carbon feedstocks. The electrochemical CO2 reduction reaction, driven via renewable-derived electricity,…
N-type organic cathode materials containing carbonyl and imine groups have emerged as promising candidates for zinc-ion batteries due to their excellent charge storage capability, which arise from the synergic storage…
The redox non-innocent bis-silylenyl ortho-carborane ligands (CCcage = o-C2B10H10, SiII = ArC(NtBu)2Si; Ar = C6H5, p–tBuC6H4), with their particular chelating and electronic properties, have been employed for the synthesis of…
Valence tautomerism in molecule-based f-block materials remains virtually elusive. As a result, the effects driving and controlling the valence conversion phenomenon are poorly understood. Herein, we unravel these fundamental factors…
We report the preparation of two Pd(II) complexes based on (CCC)-pincer-NHC (NHC = N-heterocyclic carbene) ligands. One of these complexes features an NDI unit (NDI = naphthalene-diimide) attached to the…
Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D5SC90046H, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Li Su, Yaouba Souaibou, Laurence Hôtel, Christophe Jacob,…
Chem. Sci., 2025, Advance ArticleDOI: 10.1039/D4SC08591D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Mohit Dhiman, Luis Escobar, Joseph T. Smith,…
Thin films formed by complexation of oppositely charged polyelectrolytes have significant potential in applications such as separation membranes, biocompatible or anticorrosion coatings, and drug delivery systems. While layer-by-layer deposition is…
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