A coordination polymer with a silylene-supported Pd6 core as an efficient heterogeneous hydrogenation catalyst
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Energy and Environment
The role of cytosine methylation in regulating the topology and liquid–liquid phase separation of DNA G-quadruplexes
Chem. Sci., 2025, 16,4213-4225DOI: 10.1039/D4SC06959E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Mitsuki Tsuruta, Sumit Shil, Shinya Taniguchi, Keiko Kawauchi,…
Anti-poisoning of CO and carbonyl species over Pd catalysts during the electrooxidation of ethylene glycol to glycolic acid at elevated current density
The electrocatalytic oxidation of ethylene glycol (EG) to produce valuable glycolic acid (GLYA) is a promising strategy to tackle EG overcapacity. Despite the good selectivity of Pd for EG oxidation,…
Multi-functional nitrile-based electrolyte additives enable stable lithium metal batteries with high-voltage nickel-rich cathodes
A rechargeable lithium (Li) metal anode combined with a high-voltage nickel-rich layered cathode has been considered a promising combination for high-energy Li metal batteries (LMBs). However, they usually suffer from…
Zn(ii)-driven impact of monomeric transthyretin on amyloid-β amyloidogenesis
Extracellular accumulation of amyloid-β (Aβ) peptides in the brain plays a significant role in the development of Alzheimer’s disease (AD). While the co-localization and interaction of proteins and metal ions…
An iterative synthesis of poly-substituted indole oligomers reveals a short effective conjugation length in eumelanin model compounds
Eumelanin is a multifunctional biomaterial that colors the skin, hair and eyes of mammals. Despite years of effort, its molecular structure remains unknown, limiting our understanding of its biological function…
Tuning the selectivity of P4 reduction at alkaline-earth metal centres
Reduction of P4 with β-diketiminate MgI complexes, (BDI)MgMg(BDI), depends strongly on the bulk of the ligand. Whereas superbulky BDI ligands gave selective reduction to P42− in a butterfly conformation, reduction…
Enhancing FAIRdata by providing digital workflows from data generation to the publication of data: an open source approach described for cyclic voltammetry
Chem. Sci., 2025, 16,4430-4441DOI: 10.1039/D4SC08620A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. David Herrmann, Patrick Hodapp, Martin Starman, Pei-Chi Huang,…
Debut of enzyme-responsive anionic cyanine for overlap-free NIR-II-to-I dual-channel tumour imaging
Bridging the disparity between traditional surgical resection imaging and ex vivo histopathology, fluorescence imaging is considered a promising tool in disease diagnosis and imaging navigation. Nevertheless, its usefulness is undermined…
Host–guest chemistry on living cells enabling recyclable photobiocatalytic cascade
Combining chemical and whole-cell catalysts enables sustainable chemoenzymatic cascade reactions. However, their traditional combination faces challenges in catalyst recycling and maintaining cell viability. Here, we introduce a supramolecular host–guest strategy…