Using supramolecular chiral cages to create a favorable chiral environment can effectively address the limitations of traditional metal asymmetric catalysis in controlling chiral catalytically active centers. However, achieving harmonious interactions…
The simultaneous regulation of particle size, surface coordinated environment and composition for Pt-based intermetallic compound (Pt-IMC) nanoparticles to manipulate their reactivity for energy storage is of great importance. Herein, we…
While the quantum yields of photosensitiser-derived one-electron-reduced species (OERSs) significantly impact the overall efficiencies of various redox-photosensitised photocatalytic reactions, the primary factors that influence them remain unclear. In this study,…
The water–gas shift reaction (WGSR, CO + H2O ⇔ CO2 + H2) is widely used for the upgrading of syngas, a key substrate for various chemical processes. However, the industrial…
Elucidating the photophysical mechanisms within multi-chromophore assembly (MCA) is essential for many key technological and biological processes. Although it has been established that one of the most important photoactivated applications…
Chem. Sci., 2025, 16,4360-4365DOI: 10.1039/D4SC08594A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Man Sing Wong, Utsa Karmakar, Marco Bertolini, Abigail…
A goal of molecular electronics and spintronics is to create molecular devices that change their conductance in response to external stimuli. The Aharonov–Bohm (AB) effect implies that an electronic device…
Science’s broader impacts and the historic social, political, and geographic implications of these impacts are rarely discussed in graduate STEM curricula. A new required “Scientific Responsibility and Citizenship” course for…
Chem. Sci., 2025, 16,4320-4327DOI: 10.1039/D4SC08407A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Yamato Goto, Hirohisa OhmiyaWe developed a distal C–H…
Despite the presence of pyrroloindoles in many natural products with diverse biological activities, their synthesis remains challenging in terms of stereoselectivity, especially with respect to methylation at the indole C3…
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