As economies continue to digitise, with the EU pushing to supercharge AI capabilities and Europe’s 6G vision, the need for networks to support these advancements has become more pressing.…
We present the synthesis and isolation of the first main-group phosphathioethynolates, (L = SIMes, CAACMe; SIMes = 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene, CAACMe = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene), in which phosphathioethynolate coordination occurs exclusively through the sulfur…
European Union (EU) president Ursula von der Leyen has said the EU could impose retaliatory tariffs on US digital products, according to a report in the Financial Times – a…
Transition metal-catalyzed asymmetric cyclopropanation of alkenes is an important strategy to construct chiral cyclopropane skeletons of pharmaceutical interest, but highly enantioselective and practical carbene transfer reactions based on Earth abundant…
The government is crawling towards completing the financial redress of the subpostmasters who defeated the Post Office in a group litigation order (GLO) in 2019, with 70% of remaining claims…
Precise control over chirality across hierarchical levels of peptides enriches the toolbox of peptide-based chiroptical materials. In this work, we report a controlled conversion from folded molecular chirality to supramolecular…
This perspective begins with the discovery of the Grignard reaction by a graduate student in the last years of the 19th century, before describing why it has remained largely unexplained…
Despite their unique physical properties and diverse applications in materials science, poor solubility of polycyclic aromatic hydrocarbons (PAHs) limits further fine-tuning and investigation of these systems. Herein, we report a…
The Metropolitan Police is planning to install the UK’s first permanent live facial recognition (LFR) cameras in Croydon, continuing its pattern of deploying the technology in areas where the…
The field of light-emitting two-dimensional co-assemblies (2DCAs) is extending rapidly. Nevertheless, multifluorescence tunable 2DCAs are relatively underdeveloped, because the exploration of novel assembly strategies and noncovalent interactions to realize desirable…
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