Asymmetric Intramolecular Reductive Coupling of Bisimines Templated by Chiral Diborons

Chem. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5SC03633J, Edge Article

Open Access

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Tian Chen, Hao-Yang Wang, Ronghua Xu, Guangqing Xu, He Yang, Jiangtao Sun, Lung Wa Chung, Wenjun Tang
An asymmetric intramolecular reductive coupling of bisimines has been accomplished for the first time under mild conditions with bis((+)-pinanediolato)diboron as the template, providing the unprecedented chiral dihydrophenanthrene-9,10-cis-diamines in high yields…
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