Chem. Sci., 2025, Advance Article
DOI: 10.1039/D5SC03563E, Edge Article
Open Access Open Access
Lin-Yan Bao, Rong-Wan Gao, Bo Zhu, Zhong-Min Su, Wei Guan
DFT and AIMD reveal metal valence modulation at heterointerfaces. Ni(0)-catalysed radical initiation enables facile two-component coupling, yielding enantiomers via radical bridging, with elucidated selectivity mechanisms.
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