Palladium-based coordination cages as dynamic crosslinks in acrylamide hydrogels

Chem. Sci., 2025, Advance Article
DOI: 10.1039/D5SC00335K, Edge Article

Open Access

&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Chaolei Hu, Damien W. Chen, Sylvain Sudan, Kay Severin
Hydrogels with Pd_nL_2n-type junctions can be obtained by photoinitiated copolymerization of palladium cages with acrylamide monomers in water. The dynamic nature of the cage crosslinks allows for an anion-induced switch in network topology.
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