Carboxylato-Prism[6]arene as a Supramolecular Catalyst in Water: Exploiting Its Deep Hydrophobic Cavity for Green Oxidation of Aromatic Amines

Chem. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5SC03155A, Edge Article

Open Access

&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Rocco Del Regno, Giuseppa Campanile, Placido Neri, Carmen Talotta, Antonio Rescifina, Carmelo Sgarlata, Giuseppina Domenica Giovanna Santonoceta, Carmine Gaeta, Margherita De Rosa
The carboxylato-prism[6]arene acts as an efficient catalyst for the oxidation of aromatic amines in water, utilizing hydrogen peroxide (H₂O₂) as a green oxidant. The findings indicate that forming supramolecular endo-cavity…
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