The coordination chemistry of carbene-CS2 adducts of selected NHCs and cAACs and their redox active nature in nickel complexes is reported. These azolium-2-dithiocarboxylate ligands can be considered as 1,1-isomeric dithiolene…
The present work is focused on designing novel heteroaromatic systems, formally a hybrid of dibenzooxazepines and 1,4-dihydropyrrolopyrroles (DHPPs). Straightforward synthesis affords a family of rigid, centrosymmetric, π-expanded aromatic heterocycles amenable…
Chem. Sci., 2025, 16,5118-5128DOI: 10.1039/D4SC08105F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Leon Schmidt, Kie Hankins, Lars Bläubaum, Michail Gerasimov,…
Poly(vinylidene fluoride) (PVDF)-based solid-state electrolytes (SSEs) have been considered promising candidates for advanced Li metal batteries due to their adequate mechanical strength and acceptable thermal stability. However, the poor compatibility…
The Food and Drug Administration said on Thursday that it would delay by 30 months a requirement that food companies and grocers rapidly trace contaminated food through the supply chain…
Chem. Sci., 2025, 16,5166-5173DOI: 10.1039/D4SC08569H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Ziwei Xu, Xinwen Ying, Yi Li, Xiaoyan Dong,…
Sulfur dioxide (SO2), a widely considered air pollutant, imposes major effects on ecosystems, human health, and the climate. A promising solution combines synthetic chemistry through SO2 gas capture, transforming it…
Investigating the dynamic evolution of the catalyst and regulating the structure of interfacial water molecules participating in the hydrogen oxidation reaction (HOR) are essential for developing highly efficient electrocatalysts toward…
Electrical conductivity through redox conducting MOFs (RCMOFs) proceeds by electron hopping between linkers of differing oxidation states. While this process is treated as a purely diffusional process in the literature,…
Birefringent materials, capable of manipulating light polarization, are pivotal in advanced optical technologies. Traditionally, the development of such materials has predominantly focused on purely inorganic compounds, which often exhibit limited…
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